it's not really fair to compare it to an in-browser adblocker that way, especially since using them isn't mutually exclusive. PiHole blocks ads whether you are in a browser or not, an instant benefit for everybody on your WiFi network.
Absolutely. Defense in depth; Pi-hole will cover devices that you can't install an ad-blocker on while the ad-blocker will cover some edge cases where Pi-hole can't do it.
It should never be considered an "or" situation; you want "both" as much as possible.
a lot of in browser ad blockers are based on url and css selector patterns. Meaning that if the developer updates the site which changes the dom, the ad blocker may not work.
It doesn't really do this as well as a browser adblocker, YouTube ads for example can't effectively be blocked with pihole